Daniele di Rossi and Ciro Immobile were on focus in Palermo where the 39-year-old veteran Buffon likewise won an European record 168th top, advancing one of Spain guardian Iker Casillas and Latvia's Vitalijs Astafjevs.
Italy enhanced to 13 focuses from four wins and an attract Group G, level with Spain who disarmed 4-1 Israel in Gijon from David Silva, Vitolo Machin, Diego Costa and Isco.
Somewhere else, Ireland attracted 0-0 Dublin with in a duel of unbeaten groups, with chief Seamus Coleman softening his leg up a handle from Wales' Neil Taylor who was sent off for the offense.
Ireland now impart the Group D prompt Serbia, who are likewise yet to lose and won 3-1 in Georgia.
Croatia beat Ukraine 1-0 in a Group I topper to lead by three focuses.
In Gijon, Silva made it 1-0 on 13 minutes from Jordi Alba's go for his 29th universal objective - just David Villa, Raul and Fernando Torres have scored more.
Vitolo got the second in harm time of the main half from Thiago Alcantara's pass. Costa missed a simple header two minutes into the second time frame yet he offered some kind of reparation heading in Thiago's corner on 49 minutes.
Israel scored a late relief through Lior Refaelov yet Spain expanded their lead through substitute Isco with two minutes left.
"We are beat yet we know it's a long-separate race. How about we check whether Italy can drop a point or as well. What's more, if not then we play them at home with our supporters behind us," Spain full-back Dani Carvajal said.
Italy committed no errors on the day and took a twelfth moment lead from the 2006 best on the planet De Rossi, who changed over from the spot after Sokol Cikalleshi had before debilitated for Albania.
Stationary wrapped up matters by gesturing in a cross from the privilege in the 71st after the diversion was hindered when going by fans flung smoke bombs at the Renzo Barbera.
"We gambled close to nothing and had great possibilities. We stepped forward toward the making of a solid group," Italy mentor Gian Piero Ventura said.
In the other diversion Macedonia earned their first purposes of the battle from a 3-0 triumph at minnows Liechtenstein.
In Dublin, going to Wales ruled ownership however the Euro 2016 semi-finalists neglected to get through.
Be that as it may, they were one man down when Aston Villa guard Taylor was sent off in the 69th for the handle against Everton's Seamus Coleman who was stretchered off and brought to doctor's facility with the crack.
"It's a terrible break. He's a phenomenal player and character. It's a noteworthy blow for the chap, his club and us," Ireland director Martin O'Neill disclosed to Sky TV.
Taylor will miss the following amusement in Serbia thus will genius Gareth Bale, who nearly stole a late champ from long range, over a yellow-card suspension.
In Tbilisi, Serbia switched Georgia's initial lead from Nika Katcharava because of Dusan Tadic's punishment on the stroke of half-time, a twisting shot from Aleksandar Mitrovic in the 64th and a late strike from substitute Mijat Gacinovic.
They are level at the top with Ireland on 11 focuses, with Wales and Austria - 2-0 victors over Moldova - four focuses behind.
In Group I, Fiorentina's Nikola Kalinic got Croatia's victor in the 38th moment, off Barcelona expert Ivan Rakitic.
The triumph in Zagreb gave Croatia a three-point pad, with Iceland now second because of a 2-1 triumph at Kosovo from first-half objectives from Bjoern Sigurdarson and Gylfi Sigurdsson.
Ukraine stayed on eight focuses, a stamp Turkey likewise came to from a first historically speaking home win against Finland, 2-0 in Antalya from Cenk Tosun's initial twofold.
European World Cup qualifiers proceed with nine matches Saturday, including title holders Portugal v Hungary.
World Cup 2018 hosts Russia in the mean time lost a home agreeable 2-0 against Ivory Coast, with Jonathan Kodjia and Wilfried Zaha on focus in Krasnodar.
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